面對全球溫室氣體排放量不斷上升，氣候變遷已成為這個時代最嚴峻的挑戰之一。為了因應這種挑戰，國際社會通過《巴黎協定》等多個協議，確定了全球溫室氣體淨零排放的長遠目標。欲實現這項目標，不僅需要全球各國共同努力，還需要企業界從傳統模式向可持續發展模式轉型，尋求低碳和節能的創新解決方案。能源作為全球溫室氣體排放的主要來源，其轉型尤為關鍵。傳統的化石能源不僅排放大量二氧化碳，還對自然環境造成嚴重污染。國際能源公司紛紛加快腳步從單一油氣業務向「油氣、地熱、風光發電、綠氫、儲能」等多元化能源供給型態轉型升級。對油氣企業而言，這並非一次油氣與新能源的簡單「加法」，而是一場協同發展的深度整合。透過淨零、低碳、轉型、綠氫、ESG 等多個關鍵領域的綜合應用，始能實現宏偉目標，為全球可持續發展事業注入新的動力和希望。
　　本文首先概述全球石油和天然氣產業碳排放量及擴大清潔能源轉型概況，其次探討傳統油氣產業雖正面臨著能源轉型這個全球風潮所帶來的巨大衝擊和挑戰，惟油氣資源仍是石油公司發展基石。接著，研析石油和天然氣產業淨零轉型的發展策略，朝向提供LNG、甲醇到氫、氨等脫碳的多元「綠色燃料」，以面對實現油氣生產和能源轉型的協同發展。最後綜述，從全球多地加快推動油氣與新能源整合發展，向零碳排、數位化與智慧化轉型，持續致力於油氣產業的永續經營，顯示減碳轉型是條創新發展與歷程艱辛之路！
　　In the face of rising global greenhouse gas emissions, climate change has become one of the most serious challenges of this era. In response to this challenge, the international community has established the long-term goal of net-zero global greenhouse gas emissions through multiple agreements such as the Paris Agreement. To achieve this goal, it not only requires the joint efforts of all countries around the world, but also requires the business community to transform from a traditional model to a sustainable development model and seek innovative low-carbon and energysaving solutions. As the main source of global greenhouse gas emissions, energy transformation is particularly critical. Traditional fossil energy not only emits large amounts of carbon dioxide, but also causes serious pollution to the natural environment. International energy companies have accelerated their transformation and upgrading from a single oil and gas business to diversified energy supply models such as "oil and gas, geothermal, wind and solar power generation, green hydrogen, and energy storage." For oil and gas companies, this is not a simple "addition" of oil and gas and new energy, but a deep integration of coordinated development. Through the comprehensive application of multiple key areas such as net zero, low carbon, transformation, green hydrogen, and ESG, we can achieve this ambitious goal and inject new impetus and hope into the cause of global sustainable development.
　　This article first outlines the carbon emissions of the global oil and gas industry and the expansion of clean energy transformation. Secondly, it discusses that although the traditional oil and gas industry is facing the huge impact and challenges brought by the global trend of energy transformation, oil and gas resources are still the cornerstone of the development of oil companies. Next, the development strategy for the net-zero transformation of the oil and gas industry is analyzed, aiming to provide decarbonized diversified "green fuels" such as LNG and methanol to hydrogen and ammonia, in order to achieve coordinated development of oil and gas production and energy transformation. In the final summary, many places around the world are accelerating the integrated development of oil and gas and new energy, transforming towards zero carbon emissions, digitalization and intelligence, and continuing to commit to the sustainable operation of the oil and gas industry, showing that carbon reduction transformation is a path of innovative development and an arduous journey road!

　　本論文探討了國內、外在污染場址上實施綠色及永續導向型整治（GSR）的執行方式與成果，並以中油公司新竹供油中心與台中供油中心污染場址GSR 執行成果為例進行說明。GSR 在污染場址整治中，注重平衡環境保護、社會責任與經濟效益，旨在減少整治過程中的環境衝擊，並確保土壤及地下水資源的永續利用。GSR 的核心原則包括選擇低環境影響的技術、優先使用再生能源及節能措施，以及在整治的各階段進行周密的監測與評估。此外，本研究結果顯示：GSR 亦強調了在整治過程中，積極推動公眾參與與資訊透明，以提高整治工作的信任度與接受度。
　　本研究探討國內外多個綠色整治案例顯示，透過生物復育、物理/化學整治技術和混合能源技術的應用，不僅可以有效完成污染場址的整治工作，還能提升整體環境品質。中油公司的案例成功驗證了GSR 在台灣的實施效果，並為未來類似場址的整治工作提供了重要的參考依據。透過綜合考量環境、經濟及社會三個面向，GSR 能有效減少整治過程中的負面影響，並促進資源的永續利用，為解決土壤及地下水污染問題提供了具體可行的策略。
　　GSR 理念與技術的應用，不僅能有效應對當前的環境挑戰，亦為台灣未來進行污染場址整治時，提供了強有力的技術支援。
　　This paper examines the methodology and results of Green and Sustainable Remediation (GSR) applied to contaminated sites, both domestically and internationally. It uses the remediation efforts at CPC Corporation’s Hsinchu and Taichung oil supply centers as case studies. GSR focuses on balancing environmental protection, social responsibility, and economic benefits. The goal is to reduce environmental impacts during remediation and ensure the sustainable use of soil and groundwater resources. Key principles of GSR include choosing technologies with low environmental impact, prioritizing renewable energy, and implementing energy-saving measures. The process also involves thorough monitoring and evaluation at every stage.
　　Additionally, the study emphasizes the importance of public participation and transparency in the remediation process. This approach helps build trust and increases acceptance of the remediation efforts. The analysis of several international green remediation cases shows that the use of bioremediation, physical/chemical remediation technologies, and hybrid energy technologies can effectively restore contaminated sites while improving environmental quality. The success of CPC Corporation's cases in Taiwan validates the effectiveness of GSR and provides valuable insights for future projects. By considering environmental, economic, and social factors, GSR can reduce the negative impacts of remediation and promote sustainable resource use. This approach offers a practical solution for restoring soil and groundwater contamination.
　　The adoption of GSR principles and technologies not only responses properly to current environmental challenges but also provides strong technical support for future remediation projects in Taiwan.

　　現今的岩樣熱裂分析儀，為了因應地球化學勘探的趨勢，發展出以分子量區分油氣分子族群並進行定量分析的變溫熱處理進樣模式。同時，熱脫附/熱裂解氣相層析儀也導入了程序升溫氣化注射阜與自動進樣功能，使這些儀器具備靈活設定多段升溫或持溫程序的能力，並能定量或定性不同控溫區段脫附/裂解出的碳氫化合物。因此，若要進一步瞭解受熱釋出的有機物種類與分布，以及其與生成碳氫化合物產量的關係，變溫熱處理方法將可成為研究油氣潛能的有力工具，並對過去常用於判斷生油岩特性的有機物富集度、類型及成熟度等指標，進行更廣泛且深入的探討。
　　In response to trends in geochemical exploration, modern rock pyrolysis analyzers have evolved to incorporate multi-ramp/heating rate thermal treatment techniques for samples, allowing for the differentiation of hydrocarbon molecular groups based on molecular weight and their quantitative analysis. Additionally, thermal desorption/pyrolysis gas chromatography has integrated programmed temperature vaporization injection ports and automatic sampling capabilities. These advancements enable the flexible programming of multi-ramp/heating rate processes and allow for the quantitative and qualitative analysis of hydrocarbons desorbed or pyrolyzed at different controlled temperature intervals. Therefore, to further understand the types and distribution of organic compounds released upon heating and their relationship with hydrocarbon generation yields, multi-ramp/heating rate thermal desorption and pyrolysis techniques can serve as powerful tools for studying hydrocarbon potential. They also provide a more comprehensive and in-depth analysis of traditional indicators used to evaluate source rock characteristics, such as organic richness, type, and maturity.

　　中油公司已成功將高級氧化技術(AOP)應用在煉油廠多座工場的歲修除臭清洗及空氣汙染防制，包括眞空製氣油脫硫(VGO)工場酸水氣提系統、硫磺工場鹼洗系統及污酸氣系統、蒸餾工場酸水系統、及重油轉化(RFCC)後段的轉化處理工場的液化石油氣(LPG)鹼液處理系統之除臭清洗及臭味逸散防制任務(共節省委外清洗費用7,049 萬元)。自行研發的「常溫常壓水相循環注藥清洗」方式，僅輔以常溫之氮氣通入輔助，即可使系統除臭過程中的溫度獲得有效控制，能避免委外「高溫高壓蒸氣吹驅注藥清洗」方式會有連續大量污染外排的詬病。而本除臭清洗藥劑主要係採環保無機複合配方，依各工廠(場)內製程需求或差異進行客制化清洗動線設計，因此可精準控制加藥量，因此藥劑本身不僅不會存在有機物貢獻廢水系統中額外的化學需氧量(COD)、還能再改善水質。本除臭技術可達到高度除硫除臭及削減VOC之成效(H2S削減率高達90-100%、VOC削減率高達86-99.9%)、同時能將存在於製程中的FeS(S)鈍化避免開放檢修時發生自燃的工安危害，本技術除了可減少高額委外清洗費用支出，能減少前置蒸氣吹驅時間，節省大量能耗，更能大幅縮短大修期程。
　　綜上所述，本技術除了能協助公司改善及解決工廠(場)相關環保及工安問題，未來期有機會可以對外服務，協助國內有相關需求的產業進行空污防制及改善。
　　In recent years, global environmental regulations have significantly tightened air pollution control standards. In response, the Refining & Manufacturing Research Institute of CPC Corporation Taiwan has made  breakthroughs in existing technologies and successfully applied Advanced Oxidation Processes (AOP) across various refinery facilities for odor removal during plant maintenance and air pollution control. From the end of 2022 to the present, CPC has completed odor removal and emission prevention tasks at five refinery plants, including the vacuum gas oil (VGO) acid gas stripping system, sulfur plant alkali washing system and sour gas system, distillation plant acid water system, and the LPG caustic wash system in the RFCC unit (saving NT$70.49 million in outsourcing costs).
　　CPC developed its own "ambient temperature and pressure aqueous-phase chemical cleaning" method, utilizing ambient nitrogen to assist in temperature control during the odor removal process. This avoids the common issue of continuous pollution discharge associated with outsourced "high-temperature, high-pressure steam injection cleaning." CPC’s cleaning chemicals are based on an environmentally friendly inorganic composite formula, customized according to the specific needs of each plant’s processes. This allows precise control of chemical dosage, which not only avoids adding additional Chemical Oxygen Demand (COD) to the wastewater system but also improves water quality.
　　When combined with the "ambient temperature and pressure aqueous-phase chemical cleaning" technology during plant overhauls, the system can achieve high sulfur and odor removal rates, along with significant reductions in Volatile Organic Compounds (VOC) (H2S removal of 90-100%, VOC removal of 86-99.9%). It also passivates iron sulfide (FeS(S)), preventing spontaneous combustion during open inspections, enhancing workplace safety. This AOP technology reduces substantial outsourcing costs, shortens steam purging time, conserves energy, and significantly shortens overhaul durations.
　　In summary, the AOP odor removal technology developed by CPC has been successfully applied to plant overhaul cleaning and air pollution control. It not only helps CPC address environmental and safety issues within its plants but also holds potential for external service applications, assisting other industries with air pollution prevention and improvement in the future.

　　為了提升油品品質並改善空氣污染，台灣中油公司必須降低油品的含硫量。為此，需要在煉製程序中加入觸媒，以幫助加氫脫硫反應。然而，觸媒在使用過程中容易受到有機物或金屬的沉積和毒化，導致其活性下降。當觸媒活性降低時，必須更換新的觸媒以維持轉化率，而卸下的觸媒則成為有害事業廢棄物。本研究旨在回收這些廢觸媒中的釩金屬，將其再利用製成有價值的五氧化二釩（V₂O₅），並透過電化學電解將回收之V₂O₅ 進一步製作成釩電解液用於釩液流電池(VRFB)中，由實驗結果顯示回收再製的釩電解液具有優異的導離度及能量效率，其電化學特性與商用樣品無明顯差異。同時我們也透過噴霧造粒法利用回收之V₂O₅ 與碳酸鋰(Li₂CO₃)開發快充型鋰釩氧化物(Li₃VO₄, LVO)負極材料。此快充型LVO 在0.1C 及10C 的測試條件下，分別具有403 和288 mAh/g 的克電容量，同時經過200 圈的循環測試，其電量仍舊保有91.4%。本研究成果不僅免除了中油公司龐大的廢觸媒去化問題，也具體落實了綠色循環經濟與產品高值化的目標。
　　To improve the quality of oil products and reduce air pollution, CPC Corporation, Taiwan must lower the sulfur content in its oil products. To achieve this goal, catalysts need to be added to the reactors during the refining process to assist with the hydrodesulfurization reaction. However, catalysts are prone to deactivation due to the deposition and poisoning by organic substances or metals, leading to a decline in their activity. When the catalyst's activity decreases, it must be replaced with a new one, and the spent catalyst becomes hazardous waste. This study aims to recycle the vanadium metal from these spent catalysts and reuse it to produce valuable vanadium pentoxide (V₂O₅). The recovered V₂O₅ is further processed into vanadium electrolyte through electrochemical electrolysis for use in vanadium redox flow batteries (VRFB). Experimental results show that the recycled vanadium electrolyte exhibits excellent ionic conductivity and energy efficiency, with no significant difference in electrochemical properties compared to commercial samples. Additionally, we also developed a fast-charging lithium vanadium oxide (Li₃VO₄, LVO) anode material using V₂O₅ and lithium carbonate (Li₂CO₃) through spray granulation. This fast-charging LVO anode material has a specific capacity of 403 mAh/g at 0.1C and 288 mAh/g at 10 C, and after 200 cycles of testing, it still retains 91.4% of its capacity. The results of this study not only eliminate the significant waste catalyst disposal issue for CPC Corporation but also concretely implement green circular economy and high-value product utilization.

　　新世紀科技昌明，人體基因排序奧祕已漸能解碼，生命傳承本質提升，生活工具也加速優質改良，國際日漸重視車輛排放與燃油經濟法規要求日苛，也引領車輛引擎設計及機油品質不斷提升。國內各大油公司除朝政府揭櫫節能、環保、綠色能源科技為新世紀主流先趨而努力，中油公司煉製研究所也積極配合市場營運目標，戮求前瞻、擘展未來。
　　為因應國際趨勢逐年提高汽車省油要求，經濟部能源署在2018年10月公告新版車輛容許耗能標準，新版法規省油要求平均提高3成。車廠目前採用關鍵的節能技術，包括引擎小型化、缸內汽油直噴、渦輪增壓、可變汽門正時等。同時使用這些技術是最省油的，但也會帶來問題。像是小引擎形成侷限空間，直噴技術低速時燃燒不完全容易有積碳問題，渦輪增壓讓引擎變得高溫高壓，正時系統要求精準會擔心發生磨損等。API SP最新等級機油的推出與環保法規跟車輛科技兩者的進展皆有對應，中油公司近期開發同時符合環保節能要求之國光牌9000 SP全合成機油系列，榮獲美國石油學會API SP等級認證及國家品質玉山獎，獲得車廠採用及消費者喜愛，年銷量約3000萬元，也是為台灣節能環保貢獻之最佳成果。
　　The international community has paid increasing attention to vehicle emissions and fuel economy, and regulations have become increasingly stringent led to the continuous improvement of vehicle engine design and engine oil performance. In addition to the government's announcement of energy-saving, environmentally friendly, and green energy technologies, major oil companies are also working hard for the market and look forward to the future.
　　Car manufacturers currently design new energy-saving technologies, including Downsizing, Gasoline Direct Injection, Turbocharger and Variable Valve Timing. Using these technologies together are the most fuel-efficient, but can also cause problems. The launch of the API SP grade engine oil corresponds to the purpose of both environmental protection regulations and vehicle technology. CPC 9000 SP fully synthetic engine oil series had been approval by the API and won the National Quality Yushan Award. It has been adopted by car manufacturers and consumers, with annual sales of approximately 30 million NTD. These products are also the best contribution for the energy conservation and environmental protection in Taiwan.